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Degree of unsaturation: Class 11 practice

Degree of unsaturation (double-bond equivalents) = (2C + 2 + N − H − X)/2. Read the method, follow the three worked examples, then try the six questions.

What you should know first

  • Molecular formulae

The idea behind degree of unsaturation

Degree of unsaturation (double-bond equivalents) = (2C + 2 + N − H − X)/2. Each ring or double bond counts 1; a triple bond counts 2.

Step-by-step method

  1. Count C, H, N and halogens (X).
  2. Apply the formula.
  3. Interpret as rings + π bonds.

Worked example 1 (Basic)

Find the degree of unsaturation of C₆H₆.

  1. (2 × 6 + 2 + 0 − 6 − 0)/2
  2. = 4
  3. Answer: 4

Worked example 2 (Standard)

Find the degree of unsaturation of C₂H₃Cl.

  1. (2 × 2 + 2 + 0 − 3 − 1)/2
  2. = 1
  3. Answer: 1

Worked example 3 (Challenge)

Find the degree of unsaturation of C₅H₅N.

  1. (2 × 5 + 2 + 1 − 5 − 0)/2
  2. = 4
  3. Answer: 4

Common mistakes and misconceptions

  • Ignoring halogens
  • Counting oxygen

Practice questions

  1. (Basic) Find the degree of unsaturation of C₁₀H₈.
  2. (Basic) Find the degree of unsaturation of C₆H₁₂.
  3. (Standard) Find the degree of unsaturation of C₆H₅Cl.
  4. (Standard) Find the degree of unsaturation of C₃H₆O.
  5. (Challenge) Find the degree of unsaturation of C₂H₂.
  6. (Challenge) Find the degree of unsaturation of C₇H₈.

Answer key with full working

  • Q1: (2 × 10 + 2 + 0 − 8 − 0)/2 → = 7 → Answer: 7
  • Q2: (2 × 6 + 2 + 0 − 12 − 0)/2 → = 1 → Answer: 1
  • Q3: (2 × 6 + 2 + 0 − 5 − 1)/2 → = 4 → Answer: 4
  • Q4: (2 × 3 + 2 + 0 − 6 − 0)/2 → = 1 → Answer: 1
  • Q5: (2 × 2 + 2 + 0 − 2 − 0)/2 → = 2 → Answer: 2
  • Q6: (2 × 7 + 2 + 0 − 8 − 0)/2 → = 4 → Answer: 4

Syllabus note

This skill is listed under "Organic Chemistry – Basic Principles" for Class 11 in the NCERT/CBSE books. ICSE, IGCSE, IB and state boards may teach it in a different chapter or year.

Answers on this page are generated and automatically re-checked by a second, independent calculation. They have not been reviewed by a teacher — if you spot a problem, tell us on WhatsApp.

Related practice and notes

Frequently asked questions

Which chapter is degree of unsaturation in?

"Organic Chemistry – Basic Principles", Class 11 Chemistry (NCERT/CBSE). Other boards may place it differently.

How were the answers checked?

Answers on this page are generated and automatically re-checked by a second, independent calculation. They have not been reviewed by a teacher — if you spot a problem, tell us on WhatsApp.

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