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Hybridisation and molecular shape (VSEPR): Class 11 practice

Count the electron domains around the central atom (bond pairs + lone pairs). Read the method, follow the three worked examples, then try the six questions.

What you should know first

  • Lewis structures

The idea behind hybridisation and molecular shape (vsepr)

Count the electron domains around the central atom (bond pairs + lone pairs). 2 → sp (linear), 3 → sp² (trigonal planar), 4 → sp³ (tetrahedral). Lone pairs change the shape name: NH₃ pyramidal, H₂O bent.

Step-by-step method

  1. Count bonded atoms and lone pairs on the central atom.
  2. Domains → hybridisation.
  3. Remove lone pairs to name the shape.

Worked example 1 (Basic)

Give the hybridisation and shape of C₂H₄ (each C).

  1. Bond pairs 3, lone pairs 0 → 3 domains
  2. Hybridisation sp²; shape trigonal planar
  3. Answer: sp², trigonal planar

Worked example 2 (Standard)

Give the hybridisation and shape of NH₄⁺.

  1. Bond pairs 4, lone pairs 0 → 4 domains
  2. Hybridisation sp³; shape tetrahedral
  3. Answer: sp³, tetrahedral

Worked example 3 (Challenge)

Give the hybridisation and shape of BF₃.

  1. Bond pairs 3, lone pairs 0 → 3 domains
  2. Hybridisation sp²; shape trigonal planar
  3. Answer: sp², trigonal planar

Common mistakes and misconceptions

  • Ignoring lone pairs
  • Counting a double bond as two domains

Practice questions

  1. (Basic) Give the hybridisation and shape of HCN (C).
  2. (Basic) Give the hybridisation and shape of SO₂.
  3. (Standard) Give the hybridisation and shape of H₃O⁺.
  4. (Standard) Give the hybridisation and shape of BeCl₂.
  5. (Challenge) Give the hybridisation and shape of H₂O.
  6. (Challenge) Give the hybridisation and shape of NH₃.

Answer key with full working

  • Q1: Bond pairs 2, lone pairs 0 → 2 domains → Hybridisation sp; shape linear → Answer: sp, linear
  • Q2: Bond pairs 2, lone pairs 1 → 3 domains → Hybridisation sp²; shape bent → Answer: sp², bent
  • Q3: Bond pairs 3, lone pairs 1 → 4 domains → Hybridisation sp³; shape trigonal pyramidal → Answer: sp³, trigonal pyramidal
  • Q4: Bond pairs 2, lone pairs 0 → 2 domains → Hybridisation sp; shape linear → Answer: sp, linear
  • Q5: Bond pairs 2, lone pairs 2 → 4 domains → Hybridisation sp³; shape bent → Answer: sp³, bent
  • Q6: Bond pairs 3, lone pairs 1 → 4 domains → Hybridisation sp³; shape trigonal pyramidal → Answer: sp³, trigonal pyramidal

Syllabus note

This skill is listed under "Chemical Bonding" for Class 11 in the NCERT/CBSE books. ICSE, IGCSE, IB and state boards may teach it in a different chapter or year.

Answers on this page are generated and automatically re-checked by a second, independent calculation. They have not been reviewed by a teacher — if you spot a problem, tell us on WhatsApp.

Related practice and notes

Frequently asked questions

Which chapter is hybridisation and molecular shape (vsepr) in?

"Chemical Bonding", Class 11 Chemistry (NCERT/CBSE). Other boards may place it differently.

How were the answers checked?

Answers on this page are generated and automatically re-checked by a second, independent calculation. They have not been reviewed by a teacher — if you spot a problem, tell us on WhatsApp.

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